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Shipping Hazmat: Lithium Batteries, Aerosols, and Flammables

A practical guide to shipping hazardous materials including lithium batteries, aerosol cans, and flammable products through USPS, UPS, and FedEx without getting your packages rejected.

October 31, 202511 min read
Shipping Hazmat: Lithium Batteries, Aerosols, and Flammables

Shipping Hazmat: Lithium Batteries, Aerosols, and Flammables

Last year, a seller on eBay shipped 200 portable phone chargers via USPS Priority Mail. No hazmat labels. No documentation. Just chargers tossed into poly mailers with a prayer. Three days later, a postal worker in Memphis opened a container to find a charger had swelled, ruptured, and scorched the inside of a mail sack. The seller received a $27,500 fine from the FAA and a permanent ban from USPS commercial shipping. All because they didn't know lithium batteries are classified as hazardous materials.

If you sell anything with a battery, a pressurized can, or a flammable ingredient, this article is for you. The rules are specific, the penalties are real, and the good news is that compliance isn't actually that hard once you understand the system.

What Counts as Hazmat in Shipping?

The Department of Transportation (DOT) and the International Air Transport Association (IATA) define nine classes of hazardous materials. For e-commerce sellers, three categories come up constantly:

Hazmat ClassCommon ProductsExamples
Class 3 - Flammable LiquidsPerfume, nail polish, paintAlcohol-based products over 24% ABV
Class 8 - CorrosivesCleaning products, car batteriesAnything with strong acids or bases
Class 9 - MiscellaneousLithium batteries, dry ice, magnetized materialsPower banks, laptops, e-bikes
Division 2.1 - Flammable GasAerosol cans, butane lightersHairspray, spray paint, cooking spray
Division 2.2 - Non-Flammable GasCO2 cartridges, compressed airCertain aerosol products
The mistake most sellers make is thinking "it's just a small battery" or "it's only a travel-size perfume." Size doesn't matter to the DOT. A single AA lithium battery is regulated the same way conceptually as a pallet of them — the paperwork and labeling requirements just scale differently.

Lithium Batteries: The Big One

Lithium batteries are in everything. Phones, laptops, wireless earbuds, vape pens, power tools, electric toothbrushes, kids' toys. If you sell electronics, you're shipping lithium batteries whether you realize it or not.

Two Types, Different Rules

Battery TypeChemistryFound InUN Number
Lithium-ion (Li-ion)RechargeablePhones, laptops, power banksUN3481 (packed with equipment) / UN3480 (standalone)
Lithium metalNon-rechargeableWatch batteries, some medical devicesUN3091 (packed with equipment) / UN3090 (standalone)

The Three Packing Configurations

This is where people get confused. HOW the battery relates to the device changes the rules:

  • Contained in equipment — Battery is installed in the device (phone in a box). Least restrictive.
  • Packed with equipment — Battery is separate but in the same box as the device. More documentation needed.
  • Standalone batteries — Just batteries, no device. Most restrictive. Some carriers refuse these entirely by air.
  • Carrier Rules for Lithium Batteries

    CarrierContained in DevicePacked With DeviceStandalone Batteries
    USPSGround & Air (under limits)Ground onlyGround only, max 12 per package
    UPSGround & Air with documentationGround & Air with documentationGround only
    FedExGround & Air with documentationGround & Air with documentationGround only (limited Air with contract)

    What You Actually Need to Do

    For most e-commerce sellers shipping devices with built-in batteries:

  • Mark the outer package with the lithium battery handling mark (a rectangle with the battery symbol, UN number, and your contact info). You can buy rolls of these stickers for about $15 on Amazon.
  • Include documentation inside the package stating the battery type, watt-hour rating, and that the package conforms to Section II of the relevant packing instruction.
  • Stay under the limits: For Section II (the simplified rules), lithium-ion cells must be 20 Wh or less, batteries 100 Wh or less. That covers virtually all consumer electronics.
  • Use ground shipping if you want to avoid most of the complexity. Ground shipments have far fewer restrictions than air.
  • Watt-Hour Calculations

    Carriers care about watt-hours (Wh). Here's how to calculate it:

    Watt-hours = Voltage (V) × Amp-hours (Ah)
    

    DeviceTypical BatteryWatt-HoursSection II Eligible?
    Smartphone3.7V, 3.5Ah12.95 WhYes
    Laptop11.1V, 5.0Ah55.5 WhYes
    Power bank (20,000mAh)3.7V, 20Ah74 WhYes
    E-bike battery48V, 15Ah720 WhNo — needs full hazmat shipping
    If your product exceeds 100 Wh per battery, you're in Section I territory. That means full DOT hazmat training, a hazmat shipping contract with your carrier, and significantly more packaging requirements.

    Aerosols: Hairspray to Bear Spray

    Every pressurized can is technically hazmat. Yes, even that $3 can of dry shampoo.

    Aerosol Classification

    Aerosol TypeDOT ClassORM-D Eligible?Can Ship Air?
    Flammable (hairspray, spray paint)2.1Yes, under limitsGround only via most carriers
    Non-flammable (certain medical sprays)2.2Yes, under limitsLimited air shipping
    Toxic (some pesticides)2.3NoSpecial permits only

    Shipping Aerosols by Carrier

    USPS: Aerosols can go ground only (Parcel Select Ground, Retail Ground). Maximum 16 oz per can. The package needs an ORM-D marking or the newer "Limited Quantity" diamond. USPS will not accept aerosols for any air service — period.

    UPS: Accepts aerosols via ground. Fully regulated shipping available for contract customers via air. Each package must have the DOT limited quantity marking (the diamond with "Y" marking) for quantities under the threshold.

    FedEx: Similar to UPS. Ground is straightforward with proper marking. Air requires a hazmat contract and fully compliant documentation.

    Practical Steps for Aerosol Sellers

    • Cap must be secured. Use tape or a cap lock clip.
    • Individual cans should be wrapped to prevent contact with each other.
    • Mark outer box with "Limited Quantity" diamond (at least 100mm × 100mm).
    • Maximum of 66 lb of aerosol per package for ground.
    • Never, ever try to ship aerosols internationally via air mail without full Class 2 documentation. Customs will seize the package and you may face criminal charges in certain countries.

    Flammable Liquids: Perfume, Nail Polish, and Beyond

    Anything with a flash point below 200°F (93°C) is a flammable liquid under DOT rules. That includes:

    • Perfume and cologne (alcohol-based)
    • Nail polish and nail polish remover
    • Hand sanitizer (over 24% alcohol)
    • Essential oils (many are flammable)
    • Certain cleaning products
    • Paint and paint thinner

    Quantity Limits for Ground Shipping

    Container SizeMax Per PackagePackaging Required
    Under 1 oz (30ml)12 unitsInner packaging, absorbent material
    1-16 oz (30-473ml)Based on weight limitsInner packaging, absorbent, leak-proof outer
    Over 16 oz1 gallon max for limited quantityFull DOT packaging

    The ORM-D vs Limited Quantity Transition

    ORM-D (Other Regulated Material - Domestic) markings were officially retired on January 1, 2021. The replacement is the Limited Quantity marking — a diamond shape with the top and bottom halves black, sides white. Many sellers still use ORM-D stickers and carriers still accept them domestically, but don't count on this lasting. Switch to the Limited Quantity diamond now.

    Packaging Requirements for Flammables

  • Inner containers must be sealed with no leaks.
  • Absorbent material between inner containers — enough to absorb the entire contents if all containers break simultaneously.
  • Outer packaging must be rigid (corrugated box minimum), sealed, and leak-resistant.
  • Orientation arrows ("This Side Up") on two opposite sides.
  • No mixing flammable liquids with oxidizers or corrosives in the same package.
  • Documentation You Need

    For most e-commerce shipments that fall under "limited quantity" or Section II rules, you don't need a formal hazmat shipping paper. But you do need:

    Document / LabelWhen RequiredWhere to Get It
    Lithium battery markAll lithium battery shipmentsAmazon, Uline, label printers
    Limited Quantity diamondAerosols, flammable liquids under thresholdAmazon, Uline, label printers
    Shipper's Declaration for Dangerous GoodsAir shipments of fully regulated hazmatYour carrier or IATA
    Safety Data Sheet (SDS)Keep on file; not required on packageProduct manufacturer
    UN specification packagingFully regulated hazmat onlyCertified packaging suppliers

    Penalties for Getting It Wrong

    This isn't a slap on the wrist situation:

    ViolationPenalty Range
    Shipping undeclared hazmat via air (civil)Up to $500,000 per violation
    Shipping undeclared hazmat via air (criminal)Up to $500,000 and 5 years imprisonment
    Ground shipping violationsUp to $75,000 per violation
    Repeat offendersPenalties double, possible carrier ban
    The FAA takes undeclared lithium batteries on aircraft extremely seriously. In 2024 alone, they issued over $2.5 million in fines to small business shippers.

    Quick Decision Tree

    Not sure if your product needs hazmat handling? Run through this:

  • Does it contain a lithium battery? → Follow lithium battery rules
  • Is it in a pressurized can? → Follow aerosol rules
  • Does it contain more than 24% alcohol? → Likely a flammable liquid
  • Does it have a Safety Data Sheet from the manufacturer? → Read the SDS; it tells you the hazmat class
  • None of the above? → You're probably fine, but check the SDS anyway
  • Tips from the Shipping Floor

    After handling thousands of hazmat shipments, here's what I've learned:

    • Ground shipping solves 90% of hazmat headaches. Air restrictions are strict. Ground restrictions are manageable.
    • Buy pre-printed labels in bulk. A roll of 500 lithium battery marks costs about $20. Don't handwrite these.
    • Train your warehouse staff. Even one untrained packer can ship something wrong. The DOT requires hazmat training for anyone who prepares hazmat shipments.
    • Keep an SDS file for every product you sell. When a carrier questions a shipment, the SDS is your proof of compliance.
    • When in doubt, call your carrier. UPS and FedEx both have hazmat support lines. They would rather help you ship correctly than deal with an incident.

    State-Level Regulations to Watch

    Federal DOT rules are the baseline, but some states add their own wrinkles:

    StateAdditional Requirement
    CaliforniaProp 65 warnings on products containing listed chemicals
    New YorkAdditional labeling for flammable products sold retail
    MassachusettsStricter aerosol storage limits for home-based businesses
    WashingtonE-waste battery recycling requirements affect how returns are handled
    These don't change how you ship, but they can affect what's printed on your labels and how you handle returns of hazmat products.

    Building a Hazmat Compliance Routine

    For sellers who ship hazmat products daily, build the compliance into your process so it's automatic:

  • Create a hazmat shipping station with pre-printed labels (lithium battery marks, limited quantity diamonds) and correct packaging materials ready to go.
  • Maintain a product-to-hazmat matrix — a simple spreadsheet that maps every SKU to its hazmat classification, UN number (if applicable), and required markings.
  • Train every person who packs orders. DOT requires documented hazmat training that's renewed every three years. The training doesn't need to be expensive — online courses from organizations like the Dangerous Goods Advisory Council run $100-200 per person.
  • Audit yourself quarterly. Pull 5-10 recent hazmat shipments and verify the labeling and documentation were correct. Finding your own mistakes is infinitely cheaper than a DOT inspector finding them.
  • Keep your SDS binder updated. Whenever a supplier reformulates a product, get the updated SDS. A formulation change can move a product from non-hazmat to hazmat or vice versa.
  • Hazmat shipping isn't fun. Nobody got into e-commerce because they love DOT regulations. But it's a fixed cost of doing business with these products, and the sellers who get it right never think about it again. The ones who wing it eventually get a letter from the FAA that ruins their entire quarter.

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